Acids, bases and salts are not just laboratory chemicals.
They are present in food, medicines, cleaning agents, soil, water, and even inside the human body.
This chapter explains:
- What acids, bases, and salts really are
- How they behave chemically
- Why pH matters in everyday life
- How these substances are classified and used
Understanding this chapter properly makes later topics like electrochemistry, environmental chemistry, and biology much easier.
Table of Contents
Acids: What They Really Are
An acid is a substance that produces hydrogen ions (H⁺) when dissolved in water.
Acids show their acidic nature only in aqueous solution.
Dry acids do not show acidity.
Examples:
- Hydrochloric acid (HCl)
- Sulphuric acid (H₂SO₄)
- Nitric acid (HNO₃)
Properties of Acids
Acids have certain common properties:
- They have a sour taste
- They turn blue litmus red
- They conduct electricity in aqueous solution
- They are generally corrosive
Acids react because of the presence of H⁺ ions.
Chemical Properties of Acids
Reaction with Metals
Acids react with metals to produce salt and hydrogen gas.
Example:
Zn + 2HCl → ZnCl2 + H2
Only metals above hydrogen in the reactivity series react with acids.
Reaction with Metal Carbonates and Bicarbonates
Acids react with carbonates to form:
- Salt
- Water
- Carbon dioxide
Example:
Na2CO3 + 2HCl → 2NaCl + H2O + CO2
Reaction of Acids with Bases (Neutralisation Reaction)
Acids react with bases to form salt and water.
This type of reaction is called neutralisation.
Example:
HCl + NaOH → NaCl + H2O
Explanation:
Hydrochloric acid reacts with sodium hydroxide to form sodium chloride (salt) and water.
The acidic nature of the acid and the basic nature of the base are both neutralised.
Another Example
H2SO4 + Ca(OH)2 → CaSO4 + 2H2O
Explanation:
Sulphuric acid reacts with calcium hydroxide to form calcium sulphate and water.
Classification and Industrial Uses of Acids
Strong Acids
They ionise completely in water.
Examples: HCl, H₂SO₄, HNO₃
Uses:
- Fertiliser industry
- Batteries
- Chemical manufacturing
Weak Acids
They ionise partially.
Examples: Acetic acid, Carbonic acid
Uses:
- Food preservation
- Vinegar
- Soft drinks
Bases: The Opposite Nature
A base is a substance that produces hydroxide ions (OH⁻) in aqueous solution.
Examples:
- Sodium hydroxide (NaOH)
- Calcium hydroxide [Ca(OH)₂]
Properties of Bases
- Bitter taste
- Soapy feel
- Turn red litmus blue
- Conduct electricity in solution
Chemical Properties of Bases
Reaction of Bases with Acids (Neutralisation Reaction)
Bases react with acids to form salt and water.
This reaction is called neutralisation.
Example:
NaOH + HCl → NaCl + H2O
Explanation:
Sodium hydroxide (a base) neutralises hydrochloric acid to form sodium chloride and water.
Reaction of Bases with Non-Metal Oxides
Non-metal oxides like carbon dioxide are acidic in nature.
Bases react with these acidic oxides to form salt and water.
Example:
Ca(OH)2 + CO2 → CaCO3 + H2O
Explanation: Calcium hydroxide reacts with carbon dioxide to form calcium carbonate and water. This reaction is used in the limewater test for CO₂.
Reaction of Bases with Metals
Some strong bases like sodium hydroxide react with amphoteric metals such as zinc and aluminium to produce hydrogen gas.
Example with zinc:
Zn + 2NaOH → Na2ZnO2 + H2
Example with aluminium:
2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2
Explanation:
Zinc and aluminium react with strong bases to form sodium zincate or sodium aluminate and hydrogen gas.
Basicity of an Acid and Acidity of a Base
Basicity of an Acid
Basicity of an acid = number of replaceable H⁺ ions per molecule.
Examples:
- HCl → Basicity = 1
- H₂SO₄ → Basicity = 2
Acidity of a Base
Acidity of a base = number of OH⁻ ions produced per molecule.
Examples:
- NaOH → Acidity = 1
- Ca(OH)₂ → Acidity = 2
pH Scale: Measuring Acidity and Basicity
The pH scale measures the concentration of H⁺ ions.
- pH < 7 → Acidic
- pH = 7 → Neutral
- pH > 7 → Basic
Lower pH means stronger acid.
Higher pH means stronger base.
Importance of pH in Everyday Life
pH of Soil
Incorrect pH affects crop yield.
pH of Blood
Human blood has pH around 7.4. Even slight change can be harmful.
pH of Tooth Decay
Acids produced by bacteria lower mouth pH below 5.5 and cause tooth decay.
pH of Water Bodies
Acid rain lowers pH of lakes and rivers, harming aquatic life.
Salts: Neutral Compounds
A salt is formed when an acid reacts with a base.
Salts may be:
- Neutral
- Acidic
- Basic
depending on the nature of acid and base used.
Classification of Salts – Part I
Neutral Salts
Formed from strong acid + strong base.
Example: NaCl
Acidic Salts
Formed from strong acid + weak base.
Example: NH₄Cl
Basic Salts
Formed from weak acid + strong base.
Example: Na₂CO₃
Classification of Salts – Part II
Common Salts and Uses
- Washing soda (Na₂CO₃·10H₂O) → cleaning, glass industry
- Baking soda (NaHCO₃) → baking, fire extinguishers
- Plaster of Paris (CaSO₄·½H₂O) → casts, moulds
ACIDS, BASES AND SALTS – FAQs
Why do acids show acidic nature only in water?
Because they produce H⁺ ions only in aqueous solution.
Is dry HCl acidic?
No.
Do all metals react with acids?
No, only metals above hydrogen in reactivity series
What is neutralisation reaction?
Reaction between acid and base forming salt and water.
What is basicity of an acid?
Number of replaceable hydrogen ions.
What is acidity of a base?
Number of hydroxide ions produced.
Is pH scale linear?
No, it is logarithmic.
Why is blood pH important?
Small change can be fatal.
Are all salts neutral?
No, salts can be acidic or basic.
Why is baking soda basic in nature?
Because it is a salt of weak acid and strong base.
Last Moment Notes (Cheat Sheet)
ACIDS – BASES AND SALTS
- Acid gives H⁺ ions in water
- Base gives OH⁻ ions in water
- Acids turn blue litmus red
- Bases turn red litmus blue
- Acid + Metal → Salt + H₂
- Acid + Carbonate → Salt + H₂O + CO₂
- Acid + Base → Salt + Water
- Basicity of acid = number of H⁺ ions
- Acidity of base = number of OH⁻ ions
- pH < 7 → acidic
- pH = 7 → neutral
- pH > 7 → basic
- Lower pH → stronger acid
- Higher pH → stronger base
- Strong acid + strong base → neutral salt
- Strong acid + weak base → acidic salt
- Weak acid + strong base → basic salt
- Blood pH ≈ 7.4
- Tooth decay starts below pH 5.5